You probably know that the C:\Documents and Settings folder doesn’t exist anymore in Vista. It was replaced by the C:\Users and C:\ProgramData. Vista uses symbolic links pointing to these new folders for compatibility reasons. However, many guides still refer to the old folder structure. There is a simple trick for using the old folder name in Windows Explorer, though. This way you can find configuration files easier.
If you want to see the symbolic links, you have to enable first “Show hidden files and folders” inFolder Options. To access the Folder Options you must press “ALT” in Windows Explorer to make the menu visible. You’ll find them under tools.
Now, you should be able to see Documents and Settings. But if you double click on it, you’ll get an error messages. Even administrators don’t have enough NTFS rights to navigate to this folder. It is not even possible if you change the rights by taking the ownership.